Added sections 1.1 and 1.2 (chemical & physical changes; start of pH section
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% Delete any of the following that are not needed
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\usepackage{amsmath}
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\usepackage{amsmath}
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\usepackage{amssymb}
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\usepackage{amssymb}
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\usepackage{makeidx}
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% \usepackage{makeidx}
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\usepackage{graphicx}
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\usepackage{array}
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\usepackage{multirow}
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% \usepackage{multirow}
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\usepackage{gensymb} % Just for the degree symbol
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% \usepackage{gensymb} % Just for the degree symbol
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\usepackage{ccicons} % Creative Commons icons; now we can delete an image
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% \usepackage{ccicons} % Creative Commons icons; now we can delete an image
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\usepackage{lettrine} % Drop caps
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% \usepackage{lettrine} % Drop caps
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\usepackage{wrapfig} % Let's wrap some images
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% \usepackage{wrapfig} % Let's wrap some images
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\usepackage{hanging} % For hanging indents in a script
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% \usepackage{hanging} % For hanging indents in a script
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% \usepackage{fancyvrb} % Use line numbers with code samples
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\usepackage{fvextra} % Break lines inside Verbatim environment:
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% \usepackage{fvextra} % Break lines inside Verbatim environment:
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\usepackage{enumitem} % Control spacing in lists
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\usepackage{setspace} % Better control over line-spacing
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% \usepackage{setspace} % Better control over line-spacing
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\usepackage{nicefrac} % Use nice fractions
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% \usepackage{nicefrac} % Use nice fractions
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\usepackage[bottom]{footmisc} % Keep the footnotes at the bottom of the page
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\usepackage[bottom]{footmisc} % Keep the footnotes at the bottom of the page
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\usepackage{tabto} % Use tab stops when we need to (especially in footnotes)
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% \usepackage{tabto} % Use tab stops when we need to (especially in footnotes)
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\usepackage{microtype} % Make things neater.
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\usepackage{microtype} % Make things neater.
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\usepackage{tabularray} % Easy tables
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% \usepackage{tabularray} % Easy tables
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\usepackage[]{footmisc}
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\graphicspath{{images/}} % Where are our images?
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\graphicspath{{images/}} % Where are our images?
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\usepackage{multicol} % Include two- or three-column sections
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\usepackage{multicol} % Include two- or three-column sections
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\counterwithout{footnote}{chapter} % Stop resetting the footnote count after each chapter
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\counterwithout{footnote}{chapter} % Stop resetting the footnote count after each chapter
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\NumTabs{18} % Define 18 tab stops (at 1/4" intervals) [tabto package]
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% \NumTabs{18} % Define 18 tab stops (at 1/4" intervals) [tabto package]
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\raggedbottom % Don't force text to fill page
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\setlength{\belowcaptionskip}{4pt} % Adjust space between caption and figure
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\setlength{\belowcaptionskip}{4pt} % Adjust space between caption and figure
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% \renewcommand*\contentsname{In This Issue…} % Change the name of the TOC
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% \renewcommand*\contentsname{In This Issue…} % Change the name of the TOC
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@ -208,21 +208,82 @@ If you want to donate financial support for the creation of this zine (and all t
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\setcounter{chapter}{-1}
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\setcounter{chapter}{-1}
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\chapter{Introduction}
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\chapter{Introduction}
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I've always enjoyed cleaning, but I didn't get interested in the science behind cleaning until I ready Kate Biberdorf's \textit{It's Elemental: The Hidden Chemistry in Everything} which has an entire chapter \cite[pp.~211-233]{biberdorf2021} devoted to cleaning.\footnote{She also is from the same home town as me.}
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My goal here is not to teach you how to clean everything, but how to use commonly available cleaning agents safely and effectively by teaching you how they actually do their work.
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\chapter{A Chemistry Primer}
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\section{Chemical vs. Physical Changes}
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If you remember your high school chemistry, you'll recall that substances can undergo both chemical and physical changes. Acids, bases, surfactants, enzymes, and solvents rely on chemical changes to clean things, whereas abrasives and heat rely on physical changes. However, chemical reactions are heat dependent and tend to happen more quickly at warmer temperatures, which is just one reason we wash things with warm water—it works better.
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\section{A pH Primer}
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pH is a rather vague concept for a lot of people, and the internet contains a lot of misinformation and misunderstandings about how it works as a result. Let's get that sorted out.
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pH is a measure of how acidic or alkaline (i.e., basic) a substance is. There is a lot of chemistry and math involved in pH, so let's start with some basic facts before getting into the chemistry and math.
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\begin{enumerate}[noitemsep]
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\item The pH scale goes in two directions: from 7 down to zero, and from 7 up to fourteen.
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\item Substances with a pH of 7 are neutral—they are neither acidic nor basic. (They are also very rare.)
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\item Substances with a pH less than 7 are acidic.
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\item Substances with a pH greater than 7 are basic.
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\item The further away a substance gets from 7 on the pH scale (meaning the closer it gets to either 0 or 14) the more chemically reactive a substance is. This means that it is \textit{potentially} a better cleaner, but also that it is \textit{definitely} more dangerous to use.
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\item The pH scale is unitless. That is, it does not have units like centimeters or pounds or degrees. For convenience, scientists will sometimes talk about ``pH units'' when they talk about moving up or down the scale,
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\end{enumerate}
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\subsection{Math and the pH Scale}
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The pH scale is logarithmic, rather than linear. That means that each step on the scale is multiplied or divided by a factor of ten. This can be confusing, because in our everyday lives, we are used to dealing with linear values. If one book is an inch thick, then a pile of five books will be five inches high, and a pile of 20 books will be 20 inches high.
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But logarithmic scales don't work this way. They are meant to deal with values that get very large or very small and make it possible to represent them easily on a graph.
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This means that something with a pH of 5 is not \textit{slightly} more acidic than a substance with a pH of 6; it's actually ten times more acidic. Likewise, something with a pH of 4 is ten times more acidic than something with a pH of 5, but it's also a hundred times more acidic than something with a pH of 6. Something with a pH of 3 would look like this:
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\begin{align*}
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\text{pH 3} & = 10 \times \text{pH 4} \\
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& = 100 \times \text{pH 5} \\
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& = 1000 \times \text{pH 6}
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\end{align*}
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Because the pH scale is bidirectional (that is, acidic in one direction and basic in the other), this principle also holds true for values greater than 7, but in the opposite direction:
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\begin{align*}
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\text{pH 11} & = 10 \times \text{pH 10} \\
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& = 100 \times \text{pH 9} \\
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& = 1000 \times \text{pH 8}
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\end{align*}
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In both of these examples, the values are getting closer to seven, which means that they are becoming less acidic (in the first example) and less basic (in the second example). They are, in effect, becoming more neutral.
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\subsection{The Chemistry of pH}
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\chapter{A pH Primer}
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\Chapter{Acid Cleaners}{Vinegar is your friend}
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\Chapter{Acid Cleaners}{Vinegar is your friend}
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\Chapter{Alkaline Cleaners}{When acids just won't cut it}
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\Chapter{Alkaline Cleaners}{When acids just won't cut it}
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\Chapter{Surfactants}{i.e., Soaps and detergents}
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\Chapter{Surfactants}{i.e., Soaps and detergents}
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\Chapter{Abrasive Cleaners}{Scrub-a-dub-dub}
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\Chapter{Abrasive Cleaners}{Scrub-a-dub-dub}
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\chapter{Heat}
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\chapter{Heat}
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\chapter{Enzymes}
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\chapter{Enzymes}
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\chapter{Solvents}
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I am a bit hesitant to talk about solvents here, because commercial solvents can be strong—too strong for everyday household use. Still, there are several that are available if you know where to look, including ethanol, isopropyl alcohol, acetone, mineral spirits, and turpentine.
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\end{document}
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\end{document}
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